Physical and mechanical properties
are determined according to specifications
issued by the American Dental Association
and the International Standards Organization.
The properties listed can be interpreted
as follows.
|
|
Melting Range
This is the temperature interval over
which the alloy becomes molten. The low
temperature, or solidus, is the temperature
below which the alloy is completely solid.
The high temperature, or liquidus, is
the temperature above which the alloy
is fully liquid. Between these temperatures,
both solid and liquid metal exist.
 |
The melting range tells
us a number of important things about
an alloy. |
 |
Casting temperature
is typically 100-200°F above the
liquidus. |
 |
Higher melting range
alloys typically require higher burnout
temperatures. |
 |
Alloys with liquidus
temperatures much higher than about
2100°F must be cast into high
heat (phosphate) investments. |
 |
Alloys with liquidus
temperatures much higher than about
2100°F are best cast with oxygen
fired torches. |
 |
The liquidus temperature
of a solder should be below the solidus
temperature of the alloy to be soldered. |
 |
High solidus alloys
may be (but not always are) less prone
to distortions during porcelain firing.
|
|
Coefficient of
Thermal Expansion
A measurement of the average increase
in length of a sample of the alloy over
the indicated temperature range, expressed
in mm/mm/degree C (or mm/mm/Kelvin unit).
For example, if a specimen is 10.00mm
at 25°C, and has a CTE of 14.0 x
10-6
K-1
from 25-500°C, that specimen will
be 10.0665mm long at 500°C. (14.0x10-6*10.00mm*475°C)
The CTE is primarily dependent upon
the composition of the alloy.
Very small differences in composition
do not generally result in large differences
in thermal expansion. If two manufacturers
offer two different alloys which differ
in composition by only a percent or
so, then they have the same thermal
expansion coefficient. The alloys may
be different in other qualities, such
as hardness, strength, or handling qualities,
but the thermal expansions are essentially
the same.
The reason why reported coefficients
vary so much from manufacturer to manufacturer
is simply because this is a difficult
parameter to measure with accuracy and
precision.
This is a physical property that can
provide an indication of porcelain compatibility.
It is not the definitive and absolute
compatibility indicator that many believe
it to be.
|
Density
This is the weight of one cubic centimeter
of alloy. Higher density alloys therefore
provide fewer castings per ounce than low
density alloys
|
|
Grain size
Most solid materials are crystalline,
and most metallic materials are polycrystalline.
This means that the bulk of the solid
is made up of numerous tiny interlocking
crystals of alloy.
Grain boundaries (the surfaces at which
grains meet each other) typically behave
as defects in the solid. Grain boundaries
may be weaker than the grains themselves,
for example, or non-metallic inclusions
in the alloy may accumulate at grain boundaries.
As the grain size decreases, the mechanical
properties improve as a result of the
reduction in scale of this network of
defects. In effect, the weaknesses inherent
in the alloy are distributed or "averaged
out." A fine grained alloy will have
higher Yield Strength, Ultimate Tensile
Strength, Hardness, and Elongation than
an alloy of the same composition with
a coarser grain size.
For the same reasons, finer grain alloys
tend to be less prone to hot tear cracks
during casting and solidification than
are coarse grain alloys. Hot tears are
grain boundary cracks; by making each
single grain boundary less critical to
the integrity of the solid, small cracks
at grain boundaries have less catastrophic
effects on the entire casting.
|
|
Hardness
The hardness of a material represents
its ability to resist abrasion or indentation
from a harder material. This concept
is reflected well by one of the original
hardness scales which most people heard
about at some point in grade school, called
"Moh's scale. Moh's scale is the
one that tells us that Diamond is the
hardest material on earth. This was determined
by rubbing two rocks together, and seeing
which one left scratches on the other.
Diamond scratches ruby, therefore diamond
is harder than ruby. Ruby scratches Topaz,
therefore ruby is harder than Topaz, and
so on.
While Moh's scale is easy for us to understand,
it is not very practical for dental alloys
because most alloys are somewhere between
Moh's 4 and 5, and the simple scratch
test can not distinguish one from another.
Instead, we use the Vickers hardness test.
In the Vickers test, a small pyramid shaped
diamond is pressed into the metal surface
with a fixed amount of force. The indentation
left in the metal is then measured. Larger
indentations are made in softer materials,
and smaller indentations are left in harder
materials.
While in general, harder materials have
higher yield strengths than softer materials,
technicians should be cautioned that this
is not always so, especially when comparing
alloys of different types. Additionally,
the elongation usually drops as hardness
increases, which means harder alloys may
be more brittle than softer alloys.
The hardness value by itself does not
indicate an alloy's ability to support
a load, or its ability to resist fracture.
|
Tensile
Elongation
his represents the alloys ductility or malleability.
It is the amount of permanent deformation
the alloy can withstand after it has yielded,
but before it fractures. It is one of several
properties measured in the tensile test.
|
|
Yield Strength
This is the force required to initiate
a permanent deformation in an alloy when
pulled in tension. It represents the load
carrying capacity of the alloy, and is
measured in the tensile test.
To understand the yield strength, one
must first understand a little of how
materials behave when they are stressed.
When a uniform bar of an alloy is pulled
in tension, two important things happen.
Obviously, the stress on the bar
rises. (Stress is defined as the force
per cross sectional area) Less obviously,
the length of the bar increases. A very
slight increase in length is measurable,
which increases proportionally as the
magnitude of the stress increases. If
the stress were to be removed, the bar
would return to its original length. The
distortion at this point is reversible,
or elastic.
If the stress rises to sufficient value,
a sudden extreme elongation will occur.
This extreme elongation is no longer proportional
to the stress, and it is no longer reversible.
If the load were now removed, the length
of the bar would be longer than it originally
was. The bar is said to have yielded,
and the stress level at which this yielding
occurs is the Yield Strength.
Ultimate Tensile Strength - This is the
maximum stress level which an alloy can
withstand prior to fracture.
Consider a uniform bar of alloy, pulled
in tension. As stress rises, the bar stretches
slightly until the yield strength is reached,
at which point a sudden extreme elongation
occurs as permanent deformation sets in.
Typically, the stress will continue to
rise (as the tensile elongation deformation
takes place) until just prior to fracture.
The Ultimate Tensile Strength is that
highest stress measured.
|
|
Modulus of Elasticity
This is a measurement of the stiffness
of an alloy. Just like a glass rod is
more stiff than a paper clip, some alloys
are more stiff than others.
The modulus is the proportional relationship
between stress and distortion prior to
yield. It is the amount of elastic or
reversible elongation which occurs as
the result of the stress applied.
The stiffness of an alloy is independent
of hardness, yield strength, elongation,
and ultimate tensile strength. High strength
or very hard alloys are not necessarily
very stiff. Modulus is actually most closely
related to the Coefficient of Thermal
Expansion - both are primarily dependent
upon the composition of the alloy. Palladium
is the main agent used for increasing
modulus; higher palladium alloys tend
to have higher moduli, while high gold
alloys tend to have lower moduli.
The modulus of elasticity is considered
a rather important property for PFM work,
and many consider it important in regards
to implant structures as well.
The modulus represents the amount of
distortion that occurs under a given stress,
when that stress is below the yield strength.
A lower modulus alloy will deflect more
under the same stress than will a higher
modulus alloy. Although this distortion
is reversible and disappears once the
stress is removed, the distortion experienced
during the maximum load must remain very
small or else the brittle porcelain fired
to the alloy will crack.
In regard to implants, the stiffness
issue may be related to how occlusal forces
are distributed to multiple implants.
There are two theories on this topic.
 |
Stiffer alloys are more
suited for implant work because flexing
under load is minimized, thus putting
less localized stresses on individual
implants on a multi-implant framework.
Loads are distributed better on all
implants. |
 |
Less stiff alloys are
more suited for implants because some
of the occlusal forces are absorbed
by the elastic flexing of the alloy.
|
Fortunately, the dental technician is
not forced to answer this debate, because
the range of moduli on alloys suitable
for implant work is really quite limited.
The technician often needs to balance
many design parameters, including porcelain
compatibility, melting range, cost, solderability/weldability,
and any minimum gold content requirements
placed on him or her by the implant component
supplier (many will recommend, for example,
the use of alloys with minimum gold of
50%-75%). In the end, the technician usually
has a choice of only one or two alloys,
and both typically have similar moduli.
As with the CTE, small differences in
composition do not make for large differences
in modulus. Differences in moduli seen
between manufacturers for alloys that
appear quite similar in composition are
most likely due to the strong dependence
of this measurement upon the equipment
used for the test.
|